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阴国印
时间:2022-03-09 11:29:24点击量:

阴国印

金沙8888js教授、博士生导师,国家优青获得者

地址:湖北省武汉市武昌区八一路299号,邮编:430072

邮箱:yinguoyin@whu.edu.cn


研究方向合成化学、金属催化

1.涉及金属迁移的转化反应研究:从简单原料出发,设计与探索涉及金属迁移的转化催化,合成有价值的化合物。

2.催化反应机理研究:利用物理有机化学的方法以及理论计算化学等对催化反应的机理进行详细研究


教育背景

2006.9– 2011.7 理学博士(有机化学)

中科院上海有机化学研究所,金属有机国家重点实验室导师:刘国生研究员

2002.9 – 2006.7 理学学士(应用化学)

东北农业大学,理学院导师:叶非教授、付颖教授


工作经历

2021.11–至今 金沙8888js教授、博士生导师

2016.08–2021.10 金沙8888js研究员、博士生导师

2014.11–2016.8 美国特拉华大学博士后合作导师:Donald A. Watson教授

2013.9–2014.9 德国亚琛工业大学 博士后合作导师:Franziska Schoenebeck教授

2011.11-2013.07 德国慕尼黑工业大学洪堡学者、博士后合作导师:Thorsten Bach教授


荣誉和奖励

2021年 国家自然科学基金委优秀青年基金

2017年 Thieme Chemistry Journals Award

2014年 中国科学院优秀博士学位论文

2011年 德国洪堡奖学金


独立工作后部分代表性论文:

15. Modular Access to Substituted Cyclohexanes with Kinetic Stereocontrol. Yangyang Li, Yuqiang Li, Hongjin Shi, Hong Wei, Haoyang Li, Ignacio Funes-Ardoiz* and Guoyin Yin*. Science, 2022, 376, 749–753.

 

14. Integrating Aryl Chlorides into Nickel-Catalyzed 1,1-Difunctionalization of Alkenes. Caocao Sun and Guoyin Yin*.Chin. Chem. Lett. 2022, https://doi.org/10.1016/j.cclet.2022.04.026. 

                                           

13. Catalyst-Controlled Regiodivergent 1,2-Difunctionalization of Alkenes with Two Carbon-Based Electrophiles. Md Belal#, Zheqi Li#, Lei Zhu* and Guoyin Yin*(#contributed equally to this paper).Sci. China Chem., 2022, 65, 514-520.

 12. Regio- and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis. Chao Ding, Yaoyu Ren, Caocao Sun, Jiao Long and Guoyin Yin*.J. Am. Chem. Soc., 2021, 143, 20027-20034.

 11. Synergistic Ni/Cu Catalyzed Migratory Arylsilylation of Terminal Olefins. Binzhi Zhao, Yuqiang Li, Haoyang Li, Md Belal, Lei Zhu and Guoyin Yin*.Sci. Bull., 2021, 66, 570-577. 

10.Recent Advances in the Synthesis of 1,1-Diarylalkanes by Transition-Metal Catalysis. Md Belal, Zheqi Li, Xiuqiang Lu* and Guoyin Yin*.Sci. China Chem., 2021, 64, 513-533.

9. Catalyst-Controlled Enantioselective 1,1-Arylboration of Unactivated Olefins. Wang Wang, Chao Ding and Guoyin Yin*.Nat. Catal. 2020, 3,951-958.

 

8. Modular Synthesis of Diarylalkanes by Nickel-Catalyzed 1,1-Diarylation of Unactivated Terminal Alkenes. Zheqi Li, Dong Wu, Chao Ding, Guoyin Yin*.CCS Chem. 2020, 2, 576-582.

7.Difunctionalization of Alkenes Involving Metal Migration. Yuqiang Li, Dong Wu, Hong-Gang Cheng*, Guoyin Yin*.Angew. Chem. Int. Ed. 2020, 59, 7990-8003.

 

6. Nickel-Catalyzed Chemodivergent 1,1-Difunctionalization of Unactivated alpha-Olefins with Alkynyl Electrophiles and B2pin2. Yangyang Li, Hong Wei, Dong Wu, Zheqi Li, Wang Wang, and Guoyin Yin*.ACS Catal. 2020, 10, 4888−4894

5. Reaction Scope and Mechanistic Insights of Nickel-Catalyzed Migratory Suzuki–Miyaura Cross-Coupling. Yuqiang Li, Yixin Luo, Long Peng, Yangyang Li, Binzhi Zhao, Wang Wang, Hailiang Pang, Yi Deng, Ruopeng Bai, Yu Lan* and Guoyin Yin*.Nat. Commun. 2020, 11,417.(Highlighted inSynform2020, 05,A73-A74.

4. Stereoselective Palladium-Catalyzed 1,3-Arylboration of Unconjugated Dienes for Expedient Synthesis of 1,3-Disubstituted Cyclohexanes. Hailiang Pang, Dong Wu, Hengjiang Cong, Guoyin Yin*.ACS Catal. 2019, 9, 8555–8560.

 3. Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes. Yangyang Li, Hailiang Pang, Dong Wu, Zheqi Li, Wang Wang, Hong Wei, Ying Fu, Guoyin Yin*.Angew. Chem. Int. Ed. 2019, 58,8872-8876.

 

2.Nickel-Catalyzed 1,2-Arylboration of Vinylarenes. Wang Wang, Chao Ding, Hailiang Pang, Guoyin Yin*.Org. Lett. 2019, 21, 396 -3971. 

1. Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis. Wang. Wang, Chao Ding, Yangyang Li, Zheqi Li, Yuqiang Li, Long Peng, Guoyin Yin*.Angew. Chem. Int. Ed. 2019, 58, 4612-4616.(Highlighted inSynlett 2019, 30, 1850-1854.)

 

独立之前发表的论文

1. Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Oxidative Cyclization of Enynes with Hydrogen Peroxide as the Oxidant.Angew. Chem. Int. Ed.2008,47, 5442-5445. (Featured inSynfact, 2008, 10, 1066)

2. Guosheng Liu*,Guoyin Yin, Liang Wu,Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives.Angew. Chem. Int. Ed.2008,47, 4733- 4736.

3. Tao Wu,Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Intramolecular Aaminofluorination of Unactivated Alkenes.J. Am. Chem. Soc.2009,131, 16354-16355.

4. Guoyin Yin,Yichen Wu, Guosheng Liu*, Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone.J. Am. Chem. Soc.2010,132, 11978-11987.

5. Guoyin Yin,Tao Wu,Guosheng Liu*, HighlySelective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant.Chem. Eur. J.2012, 18, 451-455.

6. Guoyin Yin, Eberhardt Herdtweck, Thorsen Bach*,Enantioselective Access to Bicyclo[4.2.0] octanes by a Sequence of [2+2] Photocycloaddition/ Reduction/Fragmentation.Chem. Eur. J.2013,19, 12639-12643.

7. Guoyin Yin, Indrek Kalvet, Ulli Englert, Franziska Schoenebeck*, Fundermental Studies and Development of Nickel-CatalyzedTrifluoromethylthiolation of Aryl Chlorides: Active Catalytic Speciesand Key Roles of Ligand and Traceless MeCN Additive Revealed.J. Am. Chem. Soc.2015.137, 4164-4172.

8. Guoyin Yin, Indrek Kalvet, Franziska Schoenebeck*, Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Pd(I) Catalyst.Angew. Chem. Int. Ed.2015,54, 6809-6813.

9. Alexander Durr#,Guoyin Yin#, Indrek Kalvet, François Napoly, Franziska Schoenebeck*, Ni-Catalyzed Trifluoromethylthiolation of Aryl Triflates.Chem. Sci.2016,7, 1076-1081. (#contributed equally to this paper)

10. Guoyin Yin,Xin Mu, Guosheng Liu*,Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center.Acc. Chem. Res.2016,49,2413-2423.

11. Scott A. Shuler,Guoyin Yin,Sarah B. Krause, Caroline M. Vesper, Donald A. Watson*Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction.J. Am. Chem. Soc.,2016,138, 13830–13833.

12. Thomas Scattolin, Erdem Senol,Guoyin Yin, Qianqian Guo, Franziska Schoenebeck*, Site-Selective C-S Bond Formation at C-Br over C-OTf and C-Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst.Angew. Chem. Int. Ed.2018,57, 12425.

对课题组感兴趣的保送生、研究生、博士后,以及研究助理,随时欢迎与阴老师联系:yinguoyin@whu.edu.cn。另外,课题组也欢迎想要进实验室做毕业设计、大创项目的本科生!


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