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07-08 2022
Copper-catalyzed regio- and stereo-selective hydrosilylation ... ​       Shaowei Chen,Xiaoqian He,Yi Jin,Yu Lan*&Xiao Shen*.Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature Communications.(沈晓、蓝宇)       Abstract:       Regioselectivity and stereoselectivity control in hydrosilylation of terminal allenes is challeging. Although the selective synthesis of vinylsilanes, branched allylsila...
05-17 2022
Dual-Resolving of Lipid Positional and Geometric Isomers of C...        Guifang Feng, Ming Gao, Liwei Wang, Jiayi Chen, Menglu Hou, Qiongqiong Wan, Yun Lin, Guoyong Xu, Xiaotian Qi & Suming Chen.Dual-resolving of positional and geometric isomers of C=C bonds via bifunctional photocycloaddition-photoisomerization reaction system.Nat. Commun.(陈素明)       Abstract:       The biological functions of lipids largely depend on their chemical structures. The po...
05-04 2022
Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Der... ​        Yizhi Zhang,Gang Zhou,Xingxing Gong,Zhuanzhuan Guo, Xiaotian Qi, Xiao Shen.Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Derived Carbenes to Alkenes.Angew. Chem. Int. Ed.(沈晓)        Abstract:        Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal complexes via singlet-metal-carbene intermediates. However, previous transition-metal-catal...
04-25 2022
Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives...         yuanyuan ping,Xiao Li,qi pan,Wangqing Kong.Ni-Catalyzed Divergent Synthesis of 2-Benzazepine Derivatives via Tunable Cyclization and 1,4-Acyl Transfer Triggered by Amide N-C Bond Cleavage.Angew. Chem. Int. Ed.(孔望清)        Abstract:        Ligand-directed divergent synthesis can transform common starting materials into distinct molecular scaffolds by simple tuning different ligands. ...
04-25 2022
Single-Junction Organic Solar Cells with 19.17% Efficiency En... ​        Rui Sun,Yao Wu,Xinrong Yang,Yuan Gao,Zeng Chen,Kai Li,Jiawei Qiao,Tao Wang,Jing Guo,Chao Liu,Xiaotao Hao,Haiming Zhu,Jie Min.Single-Junction Organic Solar Cells with 19.17% Efficiency Enabled by Introducing One Asymmetric Guest Acceptor.Advanced Materials(闵杰)        Abstract:        The ternary strategy has been widely identified as an effective approach to obtaining high-efficienc...
03-01 2022
Tailoring polymer acceptors by electron linkers for achieving... Wu, Q., Wang, W., Wu, Y., Sun, R., Guo, J., Shi, MM., Min, J.Tailoring polymer acceptors by electron linkers for achieving efficient and stable all-polymer solar cells. National Science Review.(闵杰)AbstractThe trade-off between efficiency and stability is a bit vague, and it can be tricky to precisely control the bulk morphology to simultaneously improve device efficiency and stability. Herein...
12-01 2021
A New End Group on Nonfullerene Acceptors Endows Efficient Or... Pan, YW., Zheng, XJ., Guo, J., Chen, Z., Li, SX., He, CL.,…Min, J. (2021).A New End Group on Nonfullerene Acceptors Endows Efficient Organic Solar Cells with Low Energy Losses. Advanced Functional Materials.(闵杰)AbstractLarge energy loss is one of the main limiting factors for power conversion efficiencies (PCEs) of organic solar cells (OSCs). To this effect, the chemical modifications of the...
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